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Как добавить нового суперпользователя к MySQL через командную строку

shell> mysql --user=root -p mysql
mysql> GRANT ALL PRIVILEGES ON *.* TO monty@localhost
-> IDENTIFIED BY 'some_pass' WITH GRANT OPTION;
mysql> GRANT ALL PRIVILEGES ON *.* TO monty@"%"
-> IDENTIFIED BY 'some_pass' WITH GRANT OPTION;
mysql> GRANT RELOAD,PROCESS ON *.* TO admin@localhost;
mysql> GRANT USAGE ON *.* TO dummy@localhost;

Подробнее: http://www.mysql.ru/docs/man/Adding_users.html